Product ID:CINEREX CP FIXER PART B
MSDS Date:03/19/1998
FSC:NIIN:Submitter:F BT
Status Code:A
MSDS Number: CLMCY

AGFA CORPORATION

100 CHALLENGER RD
RIDGEFIELD PARK, NJ 07660
US

Emergency Phone: 303-623-5716

Info Phone: 201-440-2500

Preparer: R. RUPPEL-KERR

Cage: 1MVW0

AGFA CORPORATION

RIDGEFIELD PARK, NJ 07660 US

Telephone: 201-440-2500

Cage: 1MVW0

ACETIC ACID

CAS: 64-19-7

RTECS: AF1225000

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ALUMINUM SULFATE

CAS: 10043-01-3

RTECS: BD1700000

ACGIH TLV: 10 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES RESPIRATORY TRACT IRRITATION;
CAUSES SKIN BURNS; CAUSES EYE BURNS; CAUSES DIGESTIVE TRACT BURNS;
IRRITATING GASES/FUMES MAY BE GIVEN OFF DURING BURNING OR THERMAL
DECOMPOSITION.
Effects of Overexposure:INHALATION: OVEREXPOSURE TO ACETIC ACID VAPORS
AND ALUMINUM SULFATE CAN CAUSE IRRITATION TO THE RESPIRATORY TRACT
RESULTING IN COUGHING, RUNNY NOSE AND SORE THROAT. SKIN: CAN CAUSE
BURNING, REDDENING, ITCHING, AND SWELLING. EYE: SEVERE IRRITATION
RESULTING IN BURNING, STINGING, REDDENING, TEARING, SWELLING AND
POSSIBLE INJURY TO THE CORNEA DEPENDING ON THE CONCENTRATION OF THE
ACID. INGESTION: SWA LLOWING CONCENTRATED ACETIC ACID MAY CAUSE
SEVERE INJURY. INGESTION OF ALUMINUM SULFATE MAY CAUSE IRRITATION
OR BURN THE DIGESTIVE TRACT.
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING EYE, SKIN
OR RESPIRATORY TRACT DISORDERS MAY BE MORE SUSCEPTIBLE TO THE
EFFECTS OF THIS PRODUCT.

First Aid:EYES: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES. SKIN: REMOVE CONTAMINATED CLOTHING, IMMEDIATELY
WASH SKIN WITH PLENTY OF WATER. WASH CLOTHING BEFORE REUSE.
INHALATION: RE MOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
IN ALL CASES, SEEK IMMEDIATE MEDICAL ATTENTION!

Flash Point:NONCOMBUSTIBLE
Extinguishing Media:MATERIAL IS NOT COMBUSTIBLE. USE EXTINGUISHING
MEDIA SUITABLE FOR OTHER COMBUSTIBLE MATERIALS IN THE AREA.
Fire Fighting Procedures:EVACUATE PERSONNEL TO A SAFE AREA. KEEP
PERSONNEL REMOVED AND UPWIND OF FIRE. WEAR SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION EMISSION OF
TOXIC FUMES OF SO2 IS POSSIBLE.

Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT
DURING CLEAN UP. DIKE SPILL. PREVENT LIQUID FROM ENTERING SEWERS,
WATERWAYS OR LOW AREAS. SOAK UP WITH SAWDUST, SAND, OIL DRY OR
OTHER ABSORBENT MATERI AL.
Neutralizing Agent:POWDERED SODIUM CARBONATE

Handling and Storage Precautions:STORE BETWEEN 40 F AND 80 F. PREFERRED
STORAGE IS AT 68 F. KEEP FROM FREEZING. AVOID EYE & SKIN
CONTACT,AND STORE IN WELL VENTILATED AREA. KEEP CONTAINER TIGHTLY
CLOSED. DO NOT STORE WITH INCOMPATIBLE MATERIALS. DO NOT STORE OR
CONSUME FOOD,DRINK OR TOBACCO IN AREA WHERE THEY MAY BECOME
CONTAMINATED
Other Precautions:KEEP OUT OF THE REACH OF CHILDREN.

Respiratory Protection:WORKPLACE AMBIENT CONCENTRATIONS SHOULD BE
MONITORED AND IF RECOMMENDED EXPOSURE LIMITS ARE EXCEEDED A
NIOSH/MSHA APPROVED RESPIRATOR SHOULD BE WORN. IF RESPIRATORS ARE
USED, INSTITUTE A PROGRAM IN A CCORDANCE WITH OSHA STANDARD
29CFR10.10.134.
Ventilation:USE SUFFICIENT GENERAL ROOM VENTILATION AND/OR LOCAL
EXHAUST TO MAINTAIN AIRBORNE LEVELS OF VAPORS BELOW APPLICABLE
EXPOSURE LIMITS.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:SAFETY GLASSES OR GOGGLES
Other Protective Equipment:APRONS. EMERGENCY SHOWERS AND EYE WASH
STATIONS SHOULD BE MADE AVAILABLE. EDUCATE AND TRAIN EMPLOYEES IN
THE SAFE USE AND HANDLING OF THIS PRODUCT.
Supplemental Safety and Health
HMIS RATINGS: HEALTH=3, FLAMMABILITY=0, REACTIVITY=0

Boiling Pt:=100.C, 212.F
Spec Gravity:1.16
pH:1.5
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR LIQUID WITH A STRONG VINEGAR ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG ALKALI, OXIDIZERS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:OXIDES OF SULFUR, CO2, CARBON
MONOXIDE.

Waste Disposal Methods:RECOVER NONUSABLE FREE LIQUID AND/OR
CONTAMINATED WATER, AND DISPOSE OF IN AN APPROVED AND PERMITTED
TREATMENT SYSTEM. REMOVE NONUSABLE SOLID MATERIAL AND/OR
CONTAMINATED SOIL, FOR DISPOSAL IN AN APP ROVED AND PERMITTED
LANDFILL. DISCHARGE TO SEWER MAY REQUIRE APPROVAL OF PERMITTING
AUTHORITY & MAY REQUIRE PRETREATMENT.

Toxicological Information:ACUTE TOXICITY: ORAL LD50: 3310 MG/KG (RAT);
DERMAL LD50: 1060 MG/KG (RABBIT) (1); INHALATION LC50: 5620 PPM/1
HR. (MOUSE) (2); EYE EFFECTS: CORROSIVE; SKIN EFFECTS: CORROSIVE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NO ECOLOGICAL INFORMATION AVAILABLE.

Transport Information:TECHNICAL SHIPPING NAME: AQUEOUS PHOTOCHEMICAL
SOLUTION CONTAINING ACETIC ACID; PRODUCT LABEL: CINEREX CP FIXER
PART B. PROPER SHIPPING NAME: ACETIC ACID SOLUTION; HAZARD CLASS:
8; UN NUMBER: UN2790 ; PACKAGING GROUP: PG II; DOT PRODUCT RQ LBS:
NONE; HAZARD LABEL: CORROSIVE; HAZARD PLACARD: CORROSIVE.

SARA Title III Information:SECTION 311/312 HAZARD CATEGORIES: IMMEDIATE
HEALTH HAZARD
Federal Regulatory Information:OSHA STATUS: THIS PRODUCT IS HAZARDOUS
UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD COMMUNICATION
STANDARD 29 CFR 1910.1200.; TSCA STATUS: ON TSCA INVENTORY; RCRA
STATUS: IF DISCARDED IN ITS PURCHASE D FORM, THIS PRODUCT WOULD NOT
BE A HAZARDOUS WASTE EITHER BY LISTING OR BY CHARACTERISTIC.
HOWEVER, UNDER RCRA, IT IS THE RESPONSIBILITY OF THE PRODUCT USER
TO DETERMINE AT THE TIME OF DISPOSAL, WHE THER A MATERIAL
CONTAINING THE PRODUCT OR DERIVED FROM THE PRODUCT SHOULD BE
CLASSIFIED AS A HAZARDO US WASTE.
State Regulatory Information:ACETIC ACID-STATE: PENNSYLVANIA, NEW
JERSEY, MASSACHUSETTS. ALUMINUM SULFATE-STATE:PENNSYLVANIA, NEW
JERSEY, MASSACHUSETTS ; WATER-STATE CODE: PENNSYLVANIA, NEW
JERSEY.